초록 |
The design and construction of molecular materials assembled in organized structures with desirable functions and properties are an area of great interest. The development of such molecular materials requires the rational design of molecular components that are programmed to assemble through non-covalent intermolecular forces, such as dipolar interactions, hydrogen bonding, shape-conforming dispersive interactions, and repulsive forces between dissimilar parts of the molecule. These interactions lead to organic nanoclusters that are regular in shape and size, and have some properties that are unlike either their molecular components or the bulk properties of similar materials. In this presentation, the formation of nanoclusters by self-assembly of conjugated rod blocks and their unique optical properties will be discussed. |