| 학회 |
한국고분자학회 |
| 학술대회 |
2006년 봄 (04/06 ~ 04/07, 일산킨텍스) |
| 권호 |
31권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Fully Crosslinked Polydivinylbenzene Microspheres by Dispersion Polymerization with Poly(styrene-b-4-vinylpyridine) as a Stabilizer |
| 초록 |
The fully crosslinked polydivinylbenzene microspheres were produced by the dispersion polymerization using poly(styrene-b-4-vinylpyridine) as the stabilizer under various polymerization conditions. The block copolymer (stabilizer) was synthesized by a reversible addition-fragmentation chain transfer (RAFT) method. Stable microspheres are made of homoaggregation (involving particles of the same type). The morphology of particle was verified using SEM and TEM. The surface morphology can be tuned by controlling the degree of block copolymer concentration, solvent and cosolvent. These microspheres crosslinked structure and highly enhanced thermal stability were verified using DSC and TGA. The glass transition temperatures region was not observed and the enhancements of the thermal stability are observed due to cross linking. |
| 저자 |
이정민, 최순자
|
| 소속 |
인하대 |
| 키워드 |
dispersion polymerization; DVB; block copolymer
|
| E-Mail |
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