| 학회 |
한국화학공학회 |
| 학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
| 권호 |
21권 1호, p.73 |
| 발표분야 |
고분자 |
| 제목 |
Synthesis and Characterization of Poly(L-Lactide-ran-ε-Caprolactam) Copolymer by Ring Opening Polymerization |
| 초록 |
Poly(L-lactide)(PLLA) is attractive material due to biocompatible and biodegradable and pharmaceutical applications, but mechanical properties of PLLA are not sufficient. Random copolymers of Poly(L-Lactide-ran-ε-Caprolactam) were synthesized by ring opening polymerization to improve mechanical properties. A process was carried out via bulk polymerization in the presence of initiator 6-aminocaproic acid and catalyst tin octoate. 6-aminocaproic acid was used as initiator of ε-caprolactam and tin octoate was used as catalyst of L-lactide. The characters of copolymers were evaluated by means of DSC, TGA, gel permeation chromatography (GPC) and 1H-NMR spectra. The varied molecular weight copolymers could be obtained within specific range of ratio between L-lactide and ε-caprolactam. The higher moiety of L-lactide led to the higher average molecular weight of copolymers. |
| 저자 |
박성현, 민진욱, 차상호
|
| 소속 |
경기대 |
| 키워드 |
ringopeningpolymerization; nylon; polylacticacid
|
| E-Mail |
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| 원문파일 |
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