학회 |
한국고분자학회 |
학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
권호 |
36권 2호 |
발표분야 |
고분자합성-구조제어중합 |
제목 |
Synthesis and Characterization of Poly[ether-b-(urea-amide)] Containing Polyamide12(PA12) Segments |
초록 |
Poly(γ-BLG)-(PA12)-Poly(γ-BLG), a A-B-A type triblock copolymer was synthesized by reaction between γ-benzyl-L-glutamate-NCA(γ-BLG) and NH2 end-capped polyamide12(PA12) oligomer. The chemical structure of the triblock copolymer was identified by using FT-IR and 1H-NMR. Poly[ether-b-(urea-amide)] block copolymer was obtained with the triblock copolymer and NCO-terminated polyether prepared by reaction isophorone diisocyanate(IPDI) to poly(tetramethylene glycol)(PTMG). The final block copolymers have relatively low melting point and high modulus, and showed typical properties of thermoplastic elastomers. |
저자 |
김두현, 이지훈, 김형중
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소속 |
공주대 |
키워드 |
polyamide; oligomer; elastomer
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E-Mail |
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