| 학회 |
한국공업화학회 |
| 학술대회 |
2005년 봄 (05/13 ~ 05/14, 충남대학교) |
| 권호 |
9권 1호 |
| 발표분야 |
전기화학 |
| 제목 |
Preparation, Morphology and Conductive Properties of Nano Sized TiO2 Filled Sulfonated Poly (Ether Ether Ketone) Nanocomposite Membranes For Direct Methanol Fuel Cell |
| 초록 |
This paper presents an evaluation of the effect of titanium dioxide nanoparticles in sulfonated poly(ether ether ketone) (SPEEK) with sulfonation degree of 57%. A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxide nanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of temperature were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. |
| 저자 |
Kprashantha1, 김한주1, 오승모2, 박수길1, Tetsuya Osaka3
|
| 소속 |
1충북대, 2서울대, 3Department of Applied Chemistry |
| 키워드 |
conductivity; water uptake; methanol permeability; morphology
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| E-Mail |
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