화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스))
권호 10권 2호
발표분야 고분자
제목 Free Radical Polymerization Use endendfuncyional group with Dibenzyl trithiocarbonate and 4-Cyanopentanoic Acid Dithiobenzoate
초록 Raft polymerization of using Dibenzyl trithiocarbonate and 4-Cyanopentanoic Acid Dithiobenzoate as a chain chain transfer agent(CTA) was studied. RAFT(Reversible Addition Fragmentation Chain Transfer) polymerization experiment use Ethyl acrylateas monomer in solution and CO2. Ethyl acrylate use experiment after purification. in times, RAFT polymerization experiment use dithiocarbonate group(ex.cumyl dithiocarbonate) as CTA. But this experiment have polymerization of using trithiocarbonate group with Dibenzyl trithiocarbonate. And, Endfunctional oligomer of having COOH group use agent as CTA.
저자 임현준, 안정호, 박윤철
소속 성균관 대
키워드 Dibenzyl trithiocarbonate; 4-Cyanopentanoic Acid Dithiobenzoate
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