| 학회 |
한국화학공학회 |
| 학술대회 |
2010년 봄 (04/22 ~ 04/23, 대구 EXCO) |
| 권호 |
16권 1호, p.889 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Synthesis of Highly Ordered Mesoporous Silver Catalyst and Pre-treatment Effect on CO Oxidation |
| 초록 |
Highly ordered mesoporous silver material was successfully synthesized from a mesoporous silica template (KIT-6) with 3-d channel structure using the nano-replication method.The effects of H2 or O2 pretreatments on the catalytic performance of the mesoporous silver were investigated using a temperature programmed CO oxidation technique in a fixed bed reactor.The mesoporous silver material that was pretreated with H2 exhibited an excellent catalytic activity compared to the as-prepared and O2-treated catalysts.For the CO oxidation, the apparent activation energy of the H2-treated mesoporous silver catalyst was 61 +/- 0.5 kJ mol-1, which was also much lower than the as-prepared (132 +/- 1.5 kJ mol-1) and O2-treated catalysts (124 +/- 1.4 kJ mol-1). Moreover, this present mesoporous silver material showed good catalytic stability. |
| 저자 |
박중남, 손정국, 김명실, 황성희, 문기영, 부진효, 한태희, 김지만
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| 소속 |
성균관대 |
| 키워드 |
Nanostructures; Mesoporous; Silver; CO oxidation; Catalyst; Pretreatment
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| E-Mail |
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| 원문파일 |
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