| 학회 |
한국고분자학회 |
| 학술대회 |
2002년 가을 (10/11 ~ 10/12, 군산대학교) |
| 권호 |
27권 2호, p.219 |
| 발표분야 |
특별 심포지엄 |
| 제목 |
Synthesis of Star-shaped Random and Block Copolymers of HEMA and MMA by Atom Transfer Radical Polymerization |
| 초록 |
Precisely controlled star-shaped polymers have been attracting interest as new polymeric materials due to their unique properties resulting from three-dimensional structures. However, construction of star-shaped polymers requires elaborated synthetic steps such as coupling of several well controlled linear polymer chains with a core molecule. Recently developed atom transfer radical polymerization opens a way to make star-shaped polymers efficiently. In this study, star-shaped poly(methyl methacrylate) with well-defined molecular weight and narrow polydispersity was prepared in high yield by Ni(PPh3)2Br2-catalyzed atom transfer radical polymerization with multifunctional initiators. This system is also applied to the synthesis of random and amphiphilic block copolymers of HEMA(2-hydroxyethyl methacrylate) and MMA. The detailed synthesis and properties of these polymers will be presented.
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| 저자 |
김미영, 인인식, 김상율
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| 소속 |
한국과학기술원 화학과 분자과학사업단 (BK21) & 기능성 고분자 연구센터 |
| 키워드 |
Atom Transfer Radical Polymerization |
| E-Mail |
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