| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Non-catalyst Synthesis of an Ionic Polyacetylene Derivative |
| 초록 |
An ionic polyacetylene derivative with azoanisole moieties was prepared by the activated polymerization of 2-ethynylpyridine by using the corresponding alkyl bromide without any additional initiator or catalyst in high yield. The chemical structure of poly[2-ethynyl-N-(p-methoxyphenylazophenyl)oxynonylpyridinium bromide] (PEMPB) was characterized by such instrumental methods as NMR (1H- and 13C-), IR, UV-visible spectroscopies to have a conjugated polymer backbone system with the designed azobenzene moieties as substituents. The electrochemical and electro-optical properties of PEMPB were studied. The cyclovoltamograms of this polymer exhibited the irreversible electrochemical behaviors between the oxidation and reduction peaks. The oxidation current density of PEMPB versus the scan rate is approximately linear relationship in the range of 30 mV/sec ~ 120 mV/sec. The photoluminescence spectrum showed that the PL peak is located at 539 nm corresponding to the photon energy of 2.30 eV. |
| 저자 |
제갈영순1, 이원철1, 진성호2, 박종욱3, 류원석4, 심상연5, 임권택6, 김상율7
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| 소속 |
1경일대, 2부산대, 3가톨릭대, 4영남대, 5강릉대, 6부경대, 7한국과학기술원 |
| 키워드 |
Synthesis; Conjugated Polymer; Eleectro-optical; Electrochemical Properties
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| E-Mail |
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