화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2011년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터)
권호 15권 1호
발표분야 환경.에너지
제목 Intrinsic kinetics of Fischer-Tropsch synthesis over a precipitated iron catalyst
초록 The kinetics of Fischer-Tropsch synthesis over a precipitated iron catalyst was studied in a 5ch fixed-bed reactor. Experimental conditions were varied as follows: H2/CO feed ratio of 0.5-2.0, reaction temperature of 528-548 K, and space velocity of 3.6-4.8 Nl/gcat·h at a constant pressure of 1.5 MPa. Finally, the reaction rate of Fischer-Tropsch synthesis, rFT,wascalculated on the base of a rate-limiting step which starts with molecularly adsorbed carbon monoxide and successive hydrogen assited dissociation with molecular hydrogen.
저자 양정일, 천동현, 양정훈, 박지찬, 김학주, 김병권, 이호태, 정헌
소속 한국에너지기술(연)
키워드 Fischer-Tropsch; Reaction kinetics; Kinetic model
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