화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2002년 봄 (04/26 ~ 04/27, 강원대학교)
권호 8권 1호, p.1785
발표분야 고분자
제목 고분자 블렌드 박막의 미세 채널 내에서의 근/장거리력 상호작용
초록 We present the surface structures formed under the void microchannels of an elastomeric mold when thin films of polystyrene/polybutadiene (PS/PB) blends are annealed with the mold placed on the film. Exactly opposite types of structure result under identical annealing conditions, depending only on the height difference in the as-cast thin film between the PS and PB phases. Recessed patterns form under the microchannel by long-range interactions when this height is more than 60nm; the usual protruding patterns result in the void microchannels due to the short-range interactions of capillarity when the height is less than 40nm. The height of fully developed meniscus of the mobile PB in solid PS is believed to be the factor that determines the type of pattern formation
저자 유필진, 서갑양, 이홍희
소속 서울대
키워드 Polymer blend; Thin film; van der Waals force; Capillarity
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