화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.2646
발표분야 분리기술
제목 Effect of Crystallization Kinetics on Defect Formation of RDX
초록 The growth kinetics of crystal of RDX was studied from different binary solutions. The relationship between surface roughness and growthkinetics was presented and discussed. A growthmechanism was identified by comparing the results with SEM and calculating the α-factors.The low heat of solution from solution depress the α-value, leading in certain cases to a rough interface with direct integration. Conversely the high heat of solution increase the α-value relative to an ideal solution, making a BCF mechanism on a smooth, The α-value calculated for the growth of RDX crystals correctly predicted a surface roughness and growth mechanism.Furthermore, the data of the growthkinetics were examined by applying the theoretical equations of the BCF and NaN models. The growthkinetics of RDX crystals were investigated from Focussed Beam Reflectance Measurement(FBRM) in- situ, in-real time.
저자 김두용1, 정재욱1, 김현수2, 김광주1
소속 1한밭대, 2국방과학(연)
키워드 RDX; Crystallization; surface roughness
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