화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터)
권호 34권 1호
발표분야 기능성 고분자
제목 Synthesis and properties of light-emitting copolymers composed of fluorene and cyanostilbene derivatives
초록 A number of polyfluorene polymers and their derivatives have been studied as emissive layers in light emitting diodes. The interest in these polymers arose because they exhibit high photoluminescence quantum yields and excellent chemical and thermal stability as well as photostability, good solubility and film-forming properties, and can readily be prepared via high-yielding synthetic routes that produce well-defined high molecular weight polymers. In this study we synthesized and characterized new fluorene-based copolymers containing low band gap cyanostilbene comonomer units. The synthesized polymers are synthesized through nickel-catalyzed Yamamoto coupling reaction. These polymers were found to be thermally stable and readily soluble in common organic solvents. The EL device with an ITO/PEDOT:PSS/Polymer/Balq/Ca configuration was fabricated using these polymers. Synthesis and electroluminescent properties of the copolymers will be discussed.
저자 미동보1, 김윤태1, 김지훈1, 이종희2, 이정익2, 박무진3, 심홍구3, 황도훈1
소속 1금오공과대, 2한국전자통신(연), 3한국과학기술원
키워드 polyfluorene copolymers; cyanostibene; electroluminescence
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