| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis and characterization of novel copolymers based on polythiophene derivatives for organic photovoltaic applications. |
| 초록 |
Here, we synthesized a novel series of solution processible thiophene polymer with a hydrogen-bond-forming urethane group in the side chain, poly[2-(3-thienyl)ethanol n-butoxycarbonylmethylurethane](PURET). Also we synthesized copolymer using mixture of PURET and P3HT. These polymers were found to be stable in common organic solvent and are easily spin-coated onto glass substrate, producing high optical quality thin films without defects .The resulting polymers were characterized elemental analysis (EA), DSC, and TGA. The bulk heterojunction solar cells with ITO/PEDOT:PSS/Polymer:PC60BM/TiOX/Al configuration were fabricated. The bulk heterojunction solar cell of blend of copolymer PURET:P3HT (ratio 1:2) and PC60BM exhibited power conversion efficiency (PCE) of 1.58% (JSC=5.58mA/cm2, VOC=0.82V, FF=34.53%) measured using AM 1.5G solar simulator at 100mW/cm2 light illumination. |
| 저자 |
김철현1, 임민정1, 송명관1, 신인애1, 진성호1, 이재욱2, 제갈영순3
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| 소속 |
1부산대, 2동아대, 3경일대 |
| 키워드 |
PURET; copolymer; bulk heterojunction solar cell
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| E-Mail |
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