| 학회 |
한국화학공학회 |
| 학술대회 |
2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터) |
| 권호 |
15권 1호, p.847 |
| 발표분야 |
재료 |
| 제목 |
Synthesis of polyphenylcarbosilane frompolymethylphenylsilane using Supercritical Cyclohexane |
| 초록 |
The synthesis of polyphenylcarbosilane (PPCS) via Kumada rearrangement of polymethylphenylsilane (PMPS) in supercritical cyclohexane was performed at various reaction conditions. Product as a SiC-precursor was analyzed by FT-IR, H NMR and GPC. Results showed that the supercritical process tends to moderate the reaction conditions such as reaction temperature and time in comparison to conventional thermal process. Supercritical cyclohexane was proven to be promising a reaction medium for the polyphenylcarbosilane production. |
| 저자 |
류재훈, 신희용, 배성열
|
| 소속 |
한양대 |
| 키워드 |
polyphenylcarbosilane; supercritical cyclohexane; Sic precursor
|
| E-Mail |
|
| 원문파일 |
초록 보기 |
