| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_환경·에너지 |
| 제목 |
A sequential approach first by reductive Ni(I) and then by oxidative Co(III) electron mediators for effective removal chlorobenzene |
| 초록 |
Removal of aliphatic or aromatic halides by oxidation leads mostly polymerization but, reduction ends in dehalogenation. Here in, oxidation followed by reduction sequentially conducted for effective removal of aromatic halide, here chlorobenzene. Electrognerated Ni(I) used to dehalogenation of chlorobenzene by means of mediated electrocatalytic reduction (MER) and then followed oxidative removal by electrogenerated Co(III) by means of mediated electrochemical oxidation (MEO) process. First, two electron mediators Co(III) and Ni(I) at each anodic and cathodic half-cells, respectively, were generated using divided paired electrolytic process. Then, the chlorobenzene gas was treated at cathodic electroscrubber for its dechlorination and sequentially treated at anodic electroscrubber for further oxidative degradation. The online FTIR results confirmed the chlorobenzene removal. |
| 저자 |
G. MUTHURAMAN, A.G.Ramu, 문일식
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| 소속 |
순천대 |
| 키워드 |
Chlorobenzene; MEO; MER; Electroscrubber.
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| E-Mail |
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