학회 | 한국공업화학회 |
학술대회 | 2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
권호 | 19권 1호 |
발표분야 | 정밀화학_포스터 |
제목 | Nitration study of pentaazapropellanes |
초록 | Explosive performances of energetic materials are influenced by their molecular structure, heats of formation, and the N/O/C balance in the molecules. Octanitrocubane (ONC) is one of the most powerful high explosives known to date. Azapropellanes with a high N/O content are rather strained but easier to synthesize than cubane. Some nitroazapropellanes with the N-NO2 groups have been calculated to release higher detonation power than well-known RDX or HMX. We have recently published the synthesis of several novel pentaaza[3.3.3]propellanes and their N-nitro derivatives as shown below. In this presentation, we will report the further nitration study of some pentaaza[3.3.3]propellanes and their characterization results. |
저자 | 이병일1, 김형태1, 신나라1, 김남태1, 오정환1, 김봉현1, 김진석2, 김영규1 |
소속 | 1서울대, 2국방과학(연) |
키워드 | High energy materials; Propellanes; Nitration |