화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터)
권호 34권 1호
발표분야 기능성 고분자
제목 Synthesis and properties of Poly (oxyethylene-b-butylene -succinate) ionomers
초록 A series of Poly(oxyethylene-b-butylene succinate)ionomers (POBSis) were synthesized by two-step polycondensation of succinic acid and mixed monomers of sodium sulfonateside chain poly(ethylene oxide)(SPEO) and 1,4-butanediol. SPEO was synthesized by grafting the sodium sulfonate on to the chain of poly(ethylene oxide)with molecular weights of 400. The compositon and structure of these segmented ionomers were determined by 1H-NMR spectroscopy. The thermal properties were investigated using DSC. The degree of crystallinity was determined by means of DSC and wide-angle X-ray scattering. A depression of melting temperature and variation of crystallinity of the hard segments with increasing content of SPEO segments were observed.
저자 김선옥1, 이청일1, 박상순2, 임승순1
소속 1한양대, 2단국대
키워드 ionomer; thermal properties
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