화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 (한-태) 전자재료의 최근 동향
제목 Synthesis and Electroluminescence Properties of New Blue Dual-Core Emitters Using Spirofluorene and Phenylcarbazole
초록 We used spirofluorene and carbazole as the side groups and substituted them into a 1-anthracen-9-yl-pyrene (AP) dual core. DSF-AP and SCP-AP were synthesized through borylation and the Suzuki aryl-aryl coupling reaction. Synthesized materials exhibited PLmax values at 443 nm and 448 nm in solution state (CHCl3), and at 458 nm and 463 nm in a thin-film state. Electroluminescence (EL) devices with the synthesized materials were fabricated. Compared with the EL device of AP core, EL device of DCP-AP showed 31% higher luminance efficiency (resulting in a value of 4.37 cd/A) and 32% higher power efficiency (to yield 1.93 lm/W), as well as a high external quantum efficiency (3.64%).
저자 박종욱1, 김범진1, 이수지2, 정효철1, 이하윤1, 강석우1
소속 1경희대, 2가톨릭대
키워드 OLED; blue; dual-core; carbazole; spirofluorene
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