초록 |
A series of ionic liquids based on morpholinium catons was prepared. N-alkyl-N-methylmorpholinium bromide, N-alkyl-N-methylmorpholinium tetrafluoroborate, N-alkyl-N-methylmorpholinium hexafluorophosphate and N-alkyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide were synthesized, and then thermal and electrochemical properties of prepared ionic liquids were measured. These morpholinium salts were found to be thermally stable near 400 oC and electrochemically stable up to 6 V at room temperature. In conclusion, these new series of morpholinium based ILs might be potential candidates for electrolytes in batteries and other electrolytic devices. |