| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Chiral Nematic Liquid Crystal Reaction Field: A Versatile Tool for Asymmetric Polymerization and Asymmetric Synthesis |
| 초록 |
We prepared a chemically stable chiral nematic liquid crystal (N*-LC) as an asymmetric reaction solvent for synthesis of helical polyacetylene (PA). The hierarchical helical structures of PA are precisely controlled by changing the screw degree or direction of the N*-LC reaction field. We extended the usage of N*-LC reaction field to synthesis of hleical aromatic conjugated polymers with circularly polarized fluoresence and to asymmetric synthesis such as Claisen rearrangement, diels-alder, and SN1 reaction. |
| 저자 |
고문주 |
| 소속 |
KIST |
| 키워드 |
Liquid Crystal; Asymmetirc Synthesis; Conjugated polymer
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| E-Mail |
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