화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터)
권호 16권 2호, p.1727
발표분야 에너지
제목 Development of MEA for PEM Fuel Cell Stacksunder Dead-End Mode
초록 In dead-end mode, PEMFC can achieve not only high fuel efficiency through minimizing fuel consumption, but the system also can be simplified because gas supply system is not required. Because dead-end stack is the closed system that outlet of anode and cathode side are blocked, the dead-end stack requires periodic venting operation at both sides to prevent decreasing performance from water accumulation. This periodic venting operation causes high pressure drop during vent valve on/off, which is followed by periodical pressure spike on MEA. In additions, because pressurized pure hydrogen and oxygen are used in dead-end mode stack, there exist potential fire hazards caused by H2/O2 gas mixture.
In this study, a 2kW-class PEMFC stack was fabricated and evaluated under dead-end mode. Experimental results indicated that several cells in stack showed low open circuit voltage after 1500hrs dead-ended operation. We drew the conclusion that this was due to the internal crossover leakage by detecting pin-holes from MEA post-mortem test. To prevent MEA failure, sub-gasket areas were extended to vulnerable areas, and its durability over 5000hrs was verified through simulated pressure shock test.
저자 김민성1, 정지훈1, 서하규1, 한인수1, 신현길1, 허태욱2, 조성백2
소속 1GS칼텍스, 2국방과학(연)
키워드 연료전지; 막전극접합체
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