화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2015년 봄 (04/22 ~ 04/24, 제주 ICC)
권호 21권 1호, p.1104
발표분야 촉매 및 반응공학
제목 Kinetics of glycerol steam reforming for hydrogen generation over Ni-Fe-Ce/Al2O3 catalyst
초록 In this study, We focused on reaction kinetics of glycerol steam reforming for hydrogen production over nickel based catalyst promoted by iron, cerium and supported over alumina. Glycerol steam reforming has been investigated in fixed-bed reactor over a wide range of W/F ratio, 0.65-2.03 g h/mol, at temperatures between 723K and 823K. Kinetic parameters for glycerol steam reforming over Ni-Fe-Ce/Al2O3 catalyst were obtained in the kinetically controlled reaction regime to ensure the absence of heat and mass transfer limitations. kinetics study was carried out using the power law equation. The activation energy and the frequency factor were calculated using Arrehenius equation.
저자 고광섭1, 이홍주1, 문동주2, 박남국1, 김영철1
소속 1전남대, 2KIST
키워드 glycerol; steam reforming; kinetics; power-law; hydrogen; catalyst; nickel
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