화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 에너지변환 및 저장시스템(분자전자 부문위원회)
제목 Controlled interface for efficient hole extraction in organic bulk heterojunction solar cells
초록 The interface between the photoactive layer and the hole extraction anode in organic bulk heterojunction solar cells is critically important to enhance the power conversion efficiency. Although significant progress has been made in organic bulk heterojunction solar cells, the detailed fundamental study on the interface control of the hole extraction layer (HEL) has not been reported so far to the best of our knowledge. We have tuned the surface work function to efficiently extract holes from poly(3-hexyl-thiophene):1-(3-methoxy-carbonyl)propyl-1-phenyl-(6,6)C61 (P3HT:PCBM) and the surface energy to control the self-organized film morphology of the photoactive layer, which have been done by treating various self-assembled monolayers (SAMs) on the layer and modifying the compositions of polymeric HEL. We have analyzed the relationship of the power conversion efficiency of the solar cells with the HEL surface work function and the self-organized P3HT:PCBM film morphology.
저자 임경근1, 이태우1, 최미리1, 김동훈1, 강남수2, 진병두3
소속 1포항공과대, 2KIST, 3단국대
키워드 photovoltaic; morphology; work function; sam
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