| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
나노바이오기술용 고분자(의료용 고분자 부문위원회) |
| 제목 |
pH-Tunable Supramolecular Networks Formed by Double-Axle Inclusion for Advanced Biomatierials |
| 초록 |
We report on supramolecular networks assembled by a unique system, named double-axle intrusion (DI) system, using gamma-cyclodextrin and the linear block copolymers grafted onto dextran, which can modulate rheological properties in response to pH changes. The supramolecular network induced drastic changes in the rheological properties in response to pH variation. Our knowledge based on supramolecular research demonstrates that such macroscopically rheological changes are results of molecularly mechanical actuations of the DI system in supramolecular networks. As a result, the molecular mobility allows to modulating the length of cross-linked part in polymeric network under pH changes. It is expected that our pH-tunable supramolecular network system can be utilized to achieve advanced functional biomaterials such as smart hydrogels and drug carriers. |
| 저자 |
Yoon Ki Joung1, Tooru Ooya2, Nobuhiko Yui3
|
| 소속 |
1Ajou Univ., 2Toyama Prefectural Univ., 3Japan Advanced Institute of Science and Technology |
| 키워드 |
Supramolecular network / double-axle intrusion / biomaterials / cyclodextrin / linear copolymer |
| E-Mail |
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