| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Solution-processable microporous molecular networks by organic sol-gel method for gas storage and separation |
| 초록 |
We synthesized microporous polyurea networks by solution-processable organic sol-gel method and studied applications for gas storage and separation of these materials. The nanoparticles, bulk and film samples of 3D crosslinked microporous polyurea networks were produced by cross-linking polymerization of tetrakis(4-aminophenyl)methane and various diisocyanate monomers. The reaction rate and mechanism of organic sol-gel polymerization were investigated by in-situ NMR. The morphological structure of various products was studied using SEM. The microporosity of the networks was characterized by carbon dioxide isotherm at 273K. The adsorption selectivity of these porous materials toward nitrogen and methane was studied. We also studied the microporosity and gas selectivity of the pyrolyzed molecular networks. (This work was supported by a Korea Science and Engineering Foundation (KOSEF) grant [2010-0026421] funded by the Korean government (MEST)) |
| 저자 |
문수영, 박지웅
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| 소속 |
광주과학기술원 |
| 키워드 |
microporous molecular networks; gas storage; gas separation; organic sol-gel
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| E-Mail |
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