화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2002년 가을 (10/11 ~ 10/12, 군산대학교)
권호 27권 2호, p.267
발표분야 고분자 구조 및 물성
제목 Nano-indentation Study of the PMDA-ODA-PDA Copolyimide Thin Films
초록 The nano-indentation study of the poly(p-phenylene pyromellitimide) (PMDA-PDA), poly(oxydiphenylene pyromellitimide)s (PMDA-ODA), and their PMDA-PDA-ODA random copolyimide thin films according to PDA contents has been examined with nano-indenter. In addition, their morphological structures were investigated with prism coupler and wide angle X-ray diffractometer. For each polyimide thin film, the hardness and modulus increase with increasing PDA contents at loads of 0.127 mN. Their birefringences increase with increasing PDA contents, and in the WAXD patterns, the polyimide thin films showed higher chain ordering along the chain plane than the chain axis according to PDA contents. Therefore, it shows that the hardness and modulus of polyimide thin films was significantly affected by their morphological structure: crystallinity, molecular order, and orientation.
Acknowledgment : This work was supported by Center for Electronic Packaging Materials of KSEF
저자 이춘근, 이보영, 설용건, 한학수
소속 연세대
키워드
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