| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Cobalt catalysts based on 4,5-bis(imino) 2,3,7,8-tetrahydro-1H,6H-acridyl ligands: Synthesis, characterization and ethylene polymerization studies. |
| 초록 |
Recently, the late transition metal catalysts for olefin polymerization have gained much attention because of their potential to yield polymers with different microstructures and their greater tolerance of functionalized monomers. Extremely active 2,6-bis(imino)pyridyl, iron- and cobalt-based catalysts for the linear polymerization of ethylene were of special interest due to their tunable steric and electronic properties which varied from polyethylene to oligomers in which both the catalytic activity and selectivity of a-olefins are highly interesting. We have developed a series of cobalt bisimino-tetrahydroacridyl catalysts for ethylene polymerization. These catalysts gave high activity with methyl aluminoxane. |
| 저자 |
비누, 김일, 하창식
|
| 소속 |
부산대 |
| 키워드 |
Late transition metal; polymerization; catalysis
|
| E-Mail |
|
