학회 |
한국공업화학회 |
학술대회 |
2011년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터) |
권호 |
15권 1호 |
발표분야 |
정밀화학 |
제목 |
Simple Rapid Method for the Synthesis of γ,γ-Diketophosphonates |
초록 |
We recently reported the synthesis of γ-hydroxy-γ-oxaphosphonates which was obtained by reacting the intermediate oxaphospholene with several aldehyde under neutral and mild conditions.We were able to obtain the phosphonate-containing aldol compounds in fairly good yield in a two-step one-pot reaction.In our attempt to extend our methodology, we now report our synthesis ofγ,γ-diketophosphonates.We have discovered by reacting the oxaphospholene intermediate with various acyl chloride under low temperature gives the desired product in quatitative yield. |
저자 |
김태우1, Tasneem Islam2, 정강연3
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소속 |
1Department of Biochemical Engineering, 2Gangneung-Wonju National Univ., 3Department of Biological |
키워드 |
γ; γ-Diketophosphonates
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E-Mail |
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