| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
| 권호 |
39권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Modular Synthesis of Fluorescent Polymer Nanoparticles from Poly(Pentafluorophenylmethacrylate) |
| 초록 |
Highly fluorescent nanoparticles are utilized extensively in a wide range of applications. One of the most predominant approaches for synthesizing fluorescent nanoparticles involve nanoprecipitation of fluorescent polymers. However, the synthesis of the fluorescent monomers and the subsequent polymerization is often cumbersome and require careful optimization and the modification of pre-formed nanostructures limits its incorporation to the surface, exposing the compounds to the external environment. Herein, we demonstrated a simple approach to prepare fluorescent polymer nanoparticles with desired emission color by modifying poly(pentafluorophenylmethacrylate) (poly(PFPMA)) with commercial dyes and subsequently nanoprecipitating the material in THF/water mixtures. The size and shape were characterized by transmission electron microscopy (TEM), dynamic light scattering (DLS), and the emission properties are studied with UV-Vis and photoluminescence (PL) spectroscopy. |
| 저자 |
이연주1, 임지우1, Sadaf Hanif2, Patrick Theato3, Jeffrey Pyun4, 차국헌5
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| 소속 |
1서울대, 2Institute of Organic Chemistry, 3Univ. of Mainz, 4Institute for Tecnnical & Macromolecular Chemistry, 5Univ. of Hamburg |
| 키워드 |
ATRP; Reactive polymer; Fluorescent polymer nanoparticles
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| E-Mail |
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