화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.2475
발표분야 Ordered nanoporous materials symposium : State of the art 2014(촉매부문위원회 주제별 심포지엄)
제목 Amine-Modified Silicates as Supports and Catalysts
초록 Amine modified porous silicates are highly versatile materials.  We have explored synthesis-structure-property relationships for these materials in the separation of organic species from gas or liquid phases, as well as for CO2 capture.1-3 Building on this, our recent endeavors in the design and application of porous silicate supported amines in catalysis will be described.  Both well-defined molecular amines and polymeric amines grafted to silicate surfaces will be discussed.  Catalysts based on discrete molecular amines that act as basic sites4-6 and polymeric amines that cap and modify the reactivity of palladium nanoparticles7 will be employed in reactions of importance in synthetic organic chemistry such as aldol condensations and selective hydrogenations, respectively.
저자 Christopher W. Jones
소속 School of Chemical & Biomolecular Engineering
키워드 Amine-Modified Silicates as Supports and Catalysts
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