화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2015년 가을 (10/21 ~ 10/23, 일산 KINTEX)
권호 21권 2호, p.2174
발표분야 촉매 및 반응공학
제목 Effect of V content, support on the propane dehydrogenation over V/MCM-41 catalysts : Comparing with Pt catalyst
초록 The lately studies for the alkane dehydrogenation catalyst are focused on vanadia catalysts supported on non-porous (SiO2), microporous (silicalite), mesoporous (MCM-41, HMS, SBA-15) and ultra-large mesoporous (MCF) silicate materials. Vanadia supported on oxides with low surface area, such as alumina, titania, magnesia, silica, have been reported to be active catalysts for the oxidative dehydrogenation (ODH) of short-chain alkanes towards the production of the respective alkenes. In this study, propane dehydrogenation on V-MCM-41 was performed. V/MCM-41 catalysts were prepared by incipient wetness impregnation method. Activity of produced V/MCM-41 catalyst is compared with V content, Pt/Al2O3 and V/Al2O3. The effect of activity by V/MCM-41 catalyst for propane dehydrogenation to propylene have been investigated by reaction test and some physicochemical characterization like X-ray diffraction(XRD), N2 adsorption-desorption(BET).
저자 이보드레, 이학범, 정재원, 고형림, 김수영
소속 한경대
키워드 propane dehydrogenation; vanadium
E-Mail
원문파일 초록 보기