| 학회 |
한국화학공학회 |
| 학술대회 |
2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터) |
| 권호 |
16권 2호, p.1183 |
| 발표분야 |
고분자 |
| 제목 |
Self-assembled Poly(aniline-co-p-phenylenediamine) Nanorods via Aqueous/ionic Liquid Interfacial Polymerization: Microwave-assisted Facile and Rapid Synthesis |
| 초록 |
This report describes the facile microwave-assisted synthesis of self-assembled copolymer, poly(aniline-co-p-phenylenediamine) [poly(Ani-co-pPD)] nanorods via aqueous/ionic liquid interfacial oxidative polymerization in the presence of acid dopants; hydrochloric acid (HCl) and p-toluene sulfonic acid (p-TSA). The method is a reliable non-template approach with ease of synthesis and economic viability for synthesizing copolymer nanostructures. Morphology of synthesized copolymer nanostructures was investigated using FE-SEM and FE-TEM, which indicate the formation of one-dimensional (1D) nanorods with average diameter of 45100 nm. FT-IR, XRD and UV-visible measurements were used to confirm the molecular and electrical structure of the doped copolymer. It is noticed that the electrical conductivity of copolymer nanorods depends upon the nature of the dopant used. We believe that this environmentally benign method can be used to synthesize nanostructures of other useful conjugated polymers. |
| 저자 |
Yuvaraj Haldorai1, Van Hoa Nguyen2, Quang Long Pham1, 심재진2
|
| 소속 |
1School of Display and Chemical Engineering, 2Yeungnam Univ. |
| 키워드 |
interfacial polymerization |
| E-Mail |
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| VOD |
VOD 보기 |
| 원문파일 |
초록 보기 |
