| 학회 |
한국공업화학회 |
| 학술대회 |
2009년 가을 (10/15 ~ 10/16, 서울산업대학교 내 서울테크노파크) |
| 권호 |
13권 2호 |
| 발표분야 |
고분자(포스터) |
| 제목 |
Radiation-crosslinked polyphenylene oxide membranes for direct methanol fuel cells |
| 초록 |
Sulfonated crosslinked polyphenylene oxide (PPO) membranes were prepared for direct methanol fuel cells. PPO membranes prepared by a solution casting were irradiated with an electron beam. Then, the irradiated membranes were sulfonated with chlorosulfonic acid. The crosslinking degree of the irradiated membranes increased with an increasing dose up to 5 MGy above which it leveled off. The thermal and mechanical properties of the irradiated PPO membranes were considerably improved due to the formation of crosslinked network in the PPO. The crosslinked PPO membranes could be sulfonated uniformly in the thickness direction by adjusting the sulfonation conditions. The ion exchange capacity and proton conductivity of the sulfonated crosslinked PPO membranes were dependant on the sulfonation degree. |
| 저자 |
이정수1, 정찬희1, 황인태1, 최재학1, 노영창1, 이영무2
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| 소속 |
1한국원자력(연), 2한양대 |
| 키워드 |
Crosslinking; E-beam; Poly(2; 6-dimethyl-1; 4-phenylene oxide); Fuel cell
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| E-Mail |
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