| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO)) |
| 권호 |
23권 1호 |
| 발표분야 |
환경·에너지_포스터 |
| 제목 |
Development of Polysulfone based Mixed Matrix Membrane for Effective CO2 Separation |
| 초록 |
Zeolitic imidazole framework 8 (ZIF-8) and amine-functionalized ZIF-8 (ZIF8-A) with 3-amino-1,2,4-triazole were prepared and used as inorganic fillers in the polyethylene glycol (PEG) grafted polysulfone (PSF) matrices (PSF-g-PEG) to fabricate mixed matrix membranes (MMMs) (ZIF-8/PSF-g-PEG and ZIF8-A/PSF-g-PEG). Incorporated ZIF-8 or ZIF8-A particles (20 wt%) in MMM were well-dispersed and adhered into the PSF-g-PEG matrices in comparison to those of the pristine PSF. Gas permeation properties with the prepared membranes were measured using time-lag method at 35 °C and 1 bar. For the polymer membranes, the PSF-g-PEG membrane showed almost 2 times higher gas permeability than PSF membrane alone due to the interaction of PEG chain and gases. The MMM of ZIF-8/PSF-g-PEG and ZIF8-A/PSF-g-PEG showed improved permeation properties on the gases, where the MMM with 61% of ZIF8-A showed the highest CO2 permeability with separation factors of CO2/N2 and CO2/CH4. |
| 저자 |
서진영1, 김세진1, 이유리1, Xuan Huy Doa2, 백경열1
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| 소속 |
1한국과학기술(연), 2한국과학기술연구워 |
| 키워드 |
Gas separation; Mixed-Matrix Membrane; Polysulfone; Poly(ethylene glycol); ZIF-8; Amine-functionalization
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| E-Mail |
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