화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2006년 봄 (04/06 ~ 04/07, 일산킨텍스)
권호 31권 1호
발표분야 기능성 고분자 나노재료
제목 Fabrication of Conducting Polymer Nanowires on Flexible Substrates by using Block Copolymer Nano-porous Templates
초록 In this study, we used polystyrene-block-poly (methyl methacrylate) copolymers (PS-b-PMMA) with PMMA cylindrical nano domains to make nano-porous structures oriented perpendicularly to the substrate. PS-b-PMMA was spin-coated onto a neutral brush modified by polystyrene-random-poly (methyl methacrylate) copolymers (PS-r-PMMA) layer attached to flexible substrates as polycarbonate(PC), poly(ethylene terephthalate)(PET). Nano porous templates with ~20nm diameter were made after UV irradiation followed by rinsing in acetic acid and ~10nm diameter was made just by rinsing in acetic acid. Hexagonally-packed nanowires of polypyrrole (PPy), poly(3,4-ethlenedioxythiophene) (PEDOT), poly(3-hexyltiophene) (P3HT) were synthesized by electrochemical-polymerization inside nano holes.
저자 이정인1, 김진곤1, 유재웅2
소속 1포항공과대, 2한국과학기술(연)
키워드 nanowires; block copolymer nano porous template
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