| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터) |
| 권호 |
38권 1호 |
| 발표분야 |
대학원생 구두발표(발표10분) |
| 제목 |
Soft-Templated-Directed Fabrication of Functional Hybrid Materials with Tailored Structures for Application in Dye-Sensitized Solar Cells |
| 초록 |
We introduce unconventional routes for the enhancement of the efficiency of TiO2-based DSSCs by incorporation of tailored hybrid nanostructures prepared from self-assembled block copolymer nanotemplates. First, Massively-ordered arrays of TiO2 dots embedded in carbon matrix were fabricated via direct carbonization of UV-stabilized PS-b-P4VP block copolymer films containing TiO2 sol-gel precursors. DSSCs containing carbon/TiO2 thin layers exhibited remarkably enhanced power conversion efficiency compared with DSSCs based on neat TiO2 NPs. Second, we introduce a new class of organic/inorganic 1D photonic crystals exhibiting stop bands in the specific wavelength range, which was created by stepwise layer-by-layer deposition of UV-crosslinked BCP inverse micelle layers. The simple yet novel 1D layered BCP films have been introduced into the back-side of the counter electrodes as light reflector in DSSCs system to increase the light harvesting of dye. |
| 저자 |
장윤희, 김동하
|
| 소속 |
이화여자대 |
| 키워드 |
Soft-Templated-Directed Fabrication; block copolymer; Dye-sensitized solar cells
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| E-Mail |
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