| 학회 |
한국공업화학회 |
| 학술대회 |
2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스)) |
| 권호 |
10권 2호 |
| 발표분야 |
촉매 |
| 제목 |
Highly Enantioselective Monoesters via-Kinetic Resolution Catalyzed by Dinuclear Chiral Co-Salen Complex Immobilized on Acid Sites of Al-MCM-41 |
| 초록 |
Among the myriad of nucleophiles that have been employed in epoxides ring openings catalyzed by chiral (salen) metal complexes, carboxylic acids have been paid very less attention. In contrast to chemo- and regioselective ring openings of terminal epoxides with carboxylic acids, only one literature is available for the enantioselective ring openings of meso epoxides using carboxylic acid as nucleophile. To broaden the application range of dinuclear chiral (salen)Co catalysts, herein we report the catalytic enantioselective ring opening of terminal epoxides with carboxylic acids. |
| 저자 |
신창교, 라울, 김건중
|
| 소속 |
인하대 |
| 키워드 |
Chirality; Co-salen; Al-MCM-41
|
| E-Mail |
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