화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자구조 및 물성
제목 Effect of POSS-PEG on Morphology and Ionic Conductivity  in Nanocomposite Polymer Electrolytes
초록 All soild-state lithium batteries will contribute to the flexible and wearable electronics and solid polymer electrolytes (SPEs) are promising candidates for replacing liquid electrolytes. Nanocomposites based on hybrid nanoparticles which are expected to exhibit both the advantages of organic and inorganic improve their properties. Hybrid nanoparticles (1 ~ 2 nm) are compatible more than inorganic filler because of their functionalized with poly(ethylene glycol) (PEG) moieties. The hybrid nanoparticles enhanced the polymer chain segmental mobility and relaxation time (τs) of nanocomposites by 1.5 times. Also the glass transition temperature of nanocomposites decreased from -30.2 to -45.3 oC and ionic conductivity increased with nanoparticle loading. Dynamics and morphology of nanocomposites depended on loading of nanoparticles.
저자 한태섭, 김광민, 이희우
소속 서강대
키워드 Nanocomposites; Solid Polymer Electrolytes; POSS-PEG
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