초록 |
In this study, the new-type Ru(bpy)32+ ECL sensor was prepared using the conductive polymer spheres in order to increase intensity. The conductive polymer ball was prepared as follow. We firstly prepared the silica nanoparticle as template by sol-gel technique in order to prepare hollow capsule sphere. The polypyrrole, polythiophene, and polyaniline hollow capsule spheres were prepared by removing core-SiO2 nanoparticle prepared by in-situ polymerization in the presence of SiO2 nanoparticle using FeCl3. Subsequently, the HCS-Nafion-modified electrode was prepared by simple hand casting composite solution with Nafion and HCS onto the surface of a carbon electrode. The prepared Ru(bpy)32+ ECL sensor was texted for TPA in order to obtain good sensitivity. |