화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 가을 (10/24 ~ 10/26, 부산 BEXCO)
권호 18권 2호, p.1473
발표분야 고분자
제목 Size- tunable dual functional mesoporous TiO2 beads for high performance dye-sensitized solar cells
초록 We successfully synthesizethemesoporous TiO2 beads, having controllable diameter in the rage from 120 to 750 nm, by solvothermal reaction with TTIP precursor and PVC-POEM graft copolymer at low temperature (at 100 oC). The prepared mesoporous TiO2 beads have the dual functions of high surface area because of the mesoporous structure and high light scattering effect because of the large size structure. The fabricated TiO2 film of photoelectrode is single titania layer composed of mesoporoussubmirometer-sized beads. Single layer reduce the fabrication process and interfacial resistance between the double layer (nanoparticle layer and scattering layer). As well as, the mesoporous TiO2 beads film showed a synergistic improvement on the charge collection efficiency resulting from the well interconnected mesopores and the strong scattering efficiency of the submirometer-sized beads, their effect improve the photoconversion efficiency.
저자 노동규, 서진아, 안성훈, 지원석, 전하림, 허성연, 김종학
소속 연세대
키워드 dye-sensitized solar cells
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