| 초록 |
We synthesized a novel photochromic polymer abbreviated as PLCP via the acrylic diene metathesis polymerization. Utilizing the combined the techniques of DSC, POM and 2D WAXD, it was realized that PLCP formed a nematic (N) LC ordered phase containing the cynclinically tilted SmC-type cybotactic clusters, in which packing structure is related to the head-to-side connected PLCP chemical structure. Additionally, we demonstrated the rewritable micro-patterned PLCP film. Due to the wireless remote controllability of reversible actuating and patterning behaviors of PLCP, it can be applied as materials in opto-electronic devices. This work was supported by the BRL 2015042417, MOTIE/KDRC 10051334, and the BK21 Plus program. |
