| 학회 |
한국화학공학회 |
| 학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
| 권호 |
21권 1호, p.1068 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Identification of active sites for the dimerization of pinenes on the solid acid catalysts |
| 초록 |
Pinene extracted from biomass can be converted to its dimers which are potential high density energy sources. We focused on the dimerization of pinenes using zirconia and sulfated zirconia. Zirconium oxide was synthesized using simple sol-gel method and then treated with sulfuric acid. The acid sites on the catalysts were characterized using N2-physisorption, NH3-TPD, and pyridine-FT-IR. The catalysis was performed, which was analyzed based on the acid sites on the catalysts. The products were measured using GC-FID, GC/MS, and GPC. The origin of catalytic activity was studied and the strategy to improve the catalytic activity was discussed. |
| 저자 |
정자경1, 최재욱1, 하정명1, 서동진1, 최정규2, 이관영2
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| 소속 |
1한국과학기술(연), 2고려대 |
| 키워드 |
dimerization; solid acid catalysts; pinene
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| E-Mail |
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| 원문파일 |
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