| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_석유화학·윤활유 |
| 제목 |
Effects of Mn promoter on mesoporous Fe2O3-ZrO2 bimetal oxides for CO hydrogenation to hydrocarbons |
| 초록 |
The ordered mesoporous Fe2O3-ZrO2 at an optimal molar ratio of Zr/Fe at ~ 0.25 showed the highest catalytic activity by maintaining its original mesoporous structures even after the reductive Fischer-Tropsch synthesis (FTS) reaction conditions. The manganese (Mn) promoter has been generally known to increase the olefin selectivity by inhibiting the readsorption of olefin intermediates for a further hydrogenation to paraffinic hydrocarbons on the Fe-based FTS catalysts. On the Fe2O3-ZrO2, 5 wt%Mn revealed the highest catalytic activity and structural stability with higher olefin selectivity. To verify the effects of Mn promoter with their surface distributions, Mn promoter was incorporated by impregnation method on the pre-synthesized Fe2O3-ZrO2 (Mn/FeZr0.25Ox) as well as by tri-metal precursors incorporation method into the hard template of the KIT-6 mesopores (FeZr0.25Mn0.05Ox). |
| 저자 |
조재민, 김병기, 배종욱
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| 소속 |
성균관대 |
| 키워드 |
Fischer-Tropsch synthesis (FTS); Ordered mesoporous Fe2O3¬-ZrO2; Mn promoter; Catalytic activity; Product distribution. |
| E-Mail |
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