| 학회 |
한국화학공학회 |
| 학술대회 |
2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터) |
| 권호 |
20권 1호, p.919 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Highly Efficient Selective Oxidation of Alcohol with a Heterogeneous Supported Ruthenium Catalyst at Room Temperature and in Air |
| 초록 |
Selective alcohol oxidation has been achieved by using inexpensive and simply prepared supported ruthenium catalyst (Ru(OH)x/MnO2) at room temperature in the presence of air. A wide variety of substrates including aromatic, hetero-atomic and allylic alcohols were converted to the desired products in excellent yield and selectivity using hexane as a cheap solvent without any additive such as inorganic bases. In addition, non-activated alcohols like alicyclic, primary and secondary aliphatic ones were selectively oxidized to the corresponding aldehydes or ketones at moderate or room temperature. The Ru(OH)x/MnO2 catalyst is easily separable and reusable for at least 10 times for benzyl alcohol without reducing its catalytic activity. |
| 저자 |
Muhammad Asif Hussain, 황승규, 김정원
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| 소속 |
강원대 |
| 키워드 |
ruthenium; heterogeneous; oxidation; alcohols; aldehydes
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| E-Mail |
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| 원문파일 |
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