| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
(특별세션) 차세대 탄소자원화 기술 현황 |
| 제목 |
Multifunctional Fe Catalysis for CO2 Transformation Reactions |
| 초록 |
Novel, efficient and multifunctional binary systems consisting of Fe-bisiminopyridine complexes and additives are presented as effective catalysts for the synthesis of cyclic carbonates from epoxides and carbon dioxide. Due to the synergistic effects arising from the presence of a hydrogen bond donor and a carbon dioxide activator in well-designed heteroleptic ligands, the catalysts exhibited excellent capabilities and selectivities in carbon dioxide utilization at 50 °C and 5 bar pressure under solvent-free conditions. The control experiments and DFT calculations proposed the cooperative mechanism with functional groups combined. The reaction scope was successfully expanded to the synthesis of oxazolidinones with N-alkyl substituted aziridines. |
| 저자 |
강은주 |
| 소속 |
경희대 |
| 키워드 |
Carbon dioxide; Fe-bisiminopyridine complex; Heteroleptic ligand system
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| E-Mail |
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