화학공학소재연구정보센터
학회 한국재료학회
학술대회 2014년 봄 (05/15 ~ 05/16, 창원컨벤션센터)
권호 20권 1호
발표분야 A. 전자/반도체 재료(Electronic and Semiconductor Materials)
제목 Epitaxial growth of B-doped epitaxial Si film by hot wire CVD
초록 We have developed a method of growing thin Si film at 600oC by hot wire CVD using a very-thin large-grained poly-Si seed layer for thin-film Si solar cells. The seed layer was prepared by crystallizing an amorphous Si film by vapor-induced crystallization using AlCl3 vapor. The average grain size of the p-type epitaxial Si layer was about 20 μm and crystallographic defects in the epitaxial layer were mainly low-angle grain boundaries and coincident-site lattice boundaries, which are special boundaries of less electrical activity. Moreover, with decreasing in-situ boron doping time, the mis-orientation angle between grain boundaries and in-grain defects in epitaxial Si decreased. Due to less defects, the epitaxial Si film was high quality evidenced from Raman and TEM analysis. The highest mobility of 360 cm2/V·s was achieved with decreasing in-situ boron doping time. The performance of our preliminary thin-film solar cells with single-side HIT structure and CoSi2 back contact was poor. However, the result showed that the epitaxial Si film can have high potential for good performance with reduced boron doping concentration.
저자 강승모1, 안경민2, 문선홍3, 안병태3
소속 1Samsung SDI, 2GS caltex, 3KAIST
키워드 epitaxial growth; poly-Si; HWCVD
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