학회 | 한국화학공학회 |
학술대회 | 2014년 가을 (10/22 ~ 10/24, 대전 DCC) |
권호 | 20권 2호, p.2082 |
발표분야 | 재료 |
제목 | Synthesis of Magnetite-Block Copolymer Nanoparticle Composites |
초록 | Magnetite and block polymer (PHEMA-b-PMMA) nanocomposite was synthesized by ATRP in an ionic liquid. Magnetite nanoparticles were firstly surface-modified with an initiator under DMF (dimethylformamide) solvent, which produced the macro-initiator Fe3O4–init which initiated the polymerization for synthesis of block polymer. After immobilization of the initiator on surface of Fe3O4, block polymer chains were grafted successfully onto the surface of Fe3O4, causing to the formation of core-shell nanostructure. The incorporation of Fe3O4 in the nano-composite was confirmed by FT-IR, XRD, TEM, NMR and XPS. This method can provide a green synthetic route that has advantages over conventional methods, such as easy separation, fast removal, and convenient recovery of solvent. Acknowledgment: This research was financially supported by the Ministry of Trade, Industry &Energy(MOTIE), Korea Institute for Advancement of Technology(KIAT) and DaeGyeong Institute for Regional Program Evaluation(DGIRPE) through the Leading Industry Development for Economic Region. |
저자 | Van Chinh Tran, Van Hoa Nguyen, Thi Toan Nguyen, 심재진 |
소속 | 영남대 |
키워드 | Magnetite; Block copolymer; Nanocomposite; Nanoparticle; Synthesis |
원문파일 | 초록 보기 |