| 초록 |
Coordination polymer particles are generally constructed through the assembly of metal ions or clusters with multitopic organic linkers. Their structural tailorability, high degree of porosity, and diverse chemical functionalities render them promising candidates for a variety of applications. Herein, Zinc-based coordination polymer nanocubes (Zn-CPNs) are successfully fabricated. In the synthesis, 2,6-bis[(4-carboxyanilino)carbonyl] pyridine ([N3]) ligand is employed as an efficient shape-directing modulator to control the size and shape of Zn-CPNs. The [N3] ligand provides plenty of active sites and beneficial defects in the structure of Zn-CPNs, which is suitable for the coordination of other functional metals. The secondary metal ion-modified Zn-CPNs exhibit enhanced catalytic performance. |
