| 초록 |
We have synthesized two dumbbell-shaped diacetylene monomers. From the x-ray diffraction patterns, it was realized that the chemical structure of diacetylene monomers affects molecular packing structure, photopolymerization and gelation property. Having specific molecular packing structure, diacetylene monomers could be polymerized. Additionally, the relationship between the chemical structures and gel property was investigated. The different supramolecular assembly caused different compatibility in organic solvents. As a result, it is very important to understand the relationship between chemical structures and packing structures for the effective topochemical polymerization and gelation of diacetylene monomers. This work was supported by BK21 Plus program, the BRL 2015042417, Mid-Career Researcher Program (2016R1A2B2011041). |
